Science Explains Ancient Copper Artifacts

Northwestern University researchers ditched many of their high-tech tools and turned to large stones, fire and some old-fashioned elbow grease to recreate techniques used by Native American coppersmiths who lived more than 600 years ago. This prehistoric approach to metalworking was part of a metallurgical analysis of copper artifacts left behind by the Mississippians of the Cahokia Mounds, who lived in southeastern Illinois from 700 until 1400 A.D. The study was published in the Journal of Archaeological Science in May.

The researchers were able to identify how the coppersmiths of Cahokia likely set up their workshop and the methods and tools used to work copper nuggets into sacred jewelry, headdresses, breastplates and other regalia.

"Metals store clues within their structure that can help explain how they were processed," said David Dunand, the James N. and Margie M. Krebs Professor of materials science and engineering at Northwestern's McCormick School of Engineering and Applied Science and co-author of the paper. "We were lucky enough to analyze small, discarded pieces of copper found on the ground of the excavated 'copper workshop house in Cahokia and determine how the metal was worked by the Cahokians."

Two materials science and engineering students conducted much of the research. Matt Chastain, a Northwestern undergraduate at the time of the study, worked alongside Alix Deymier-Black, a graduate student in the materials science and engineering department. Chastain, first author of the paper, undertook the metallurgical analysis of the samples, supplied from ongoing excavations at Mound 34 in Cahokia. Chastain followed up his analysis by volunteering at the excavation site.

"We cut through some samples of the copper pieces and polished them to look at the grain structures of the copper with a microscope," said Deymier-Black, second author of the paper. "From the size, shape and features of the grains inside the copper, we determined that the coppersmiths were likely hammering the copper, probably with a heavy rock, then putting the copper in the hot coals of a wood fire for five to 10 minutes to soften it and repeating the cycle until they had created a thin sheet of copper. "