Sunday, August 28, 2011

Researchers Find Fat Turns İnto Soap İn Sewers, Contributes To Overflows

Researchers from North Carolina State University have discovered how fat, oil and grease (FOG) can create hardened deposits in sewer lines: it turns into soap! The hardened deposits, which can look like stalactites, contribute to sewer overflows. "We found that FOG deposits in sewage collection systems are created by chemical reactions that turn the fatty acids from FOG into, basically, a huge lump of soap," says Dr. Joel Ducoste, a professor of civil, construction and environmental engineering at NC State and co-author of a paper describing the research. Collection systems are the pipes and pumping stations that carry wastewater from homes and businesses to sewage-treatment facilities.

These hardened FOG deposits reduce the flow of wastewater in the pipes, contributing to sewer overflows – which can cause environmental and public-health problems and lead to costly fines and repairs.

The research team used a technique called Fourier Transform Infrared (FTIR) spectroscopy to determine what the FOG deposits were made of at the molecular level. FTIR spectroscopy shoots a sample material with infrared light at various wavelengths. Different molecular bonds vibrate in response to different wavelengths. By measuring which infrared wavelengths created vibrations in their FOG samples, researchers were able to determine each sample's molecular composition.

Using this technique, researchers confirmed that the hardened deposits were made of calcium-based fatty acid salts – or soap.

"FOG itself cannot create these deposits," Ducoste says. "The FOG must first be broken down into its constituent parts: glycerol and free fatty acids. These free fatty acids – specifically, saturated fatty acids – can react with calcium in the sewage collection system to form the hardened deposits.

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